Napoleaova is a former footballer who represented her country at under-17 level and played for AC Sparta Prague before an injury halted her career.
Having only taken up golf at the age of 20, she turned professional just three and a half years later.
Napoleaova claimed her maiden Ladies European Tour title earlier this year, winning the Amundi German Masters with a birdie on the first hole of a play-off with Cara Gainer.